Mr. and Mrs. Smith are no more.

According to TMZ Angelina Jolie filed for divorce from Brad Pitt on September 15 citing irreconcilable differences.

Jolie's decision "has to do with the way Brad was parenting the children ... she was extremely upset with his methods," reports TMZ. She is seeking physical custody of the couple's six children.

The Hollywood power couple have been together since 2004, but announced that they wouldn't marry until same-sex marriage was legal in the U.S. They eventually secretly wed in 2014—a year before the Supreme Court made gay marriage legal nationwide.

Jennifer Aniston could not be reached for a comment.